block: fix bad definition of BIO_RW_SYNC

We can't OR shift values, so get rid of BIO_RW_SYNC and use BIO_RW_SYNCIO
and BIO_RW_UNPLUG explicitly. This brings back the behaviour from before
213d9417.

Signed-off-by: Jens Axboe <jens.axboe@oracle.com>